14-(1,3-Benzodioxol-5-yl)-7,14-dihydrodibenzo[a,j]acridine
نویسندگان
چکیده
The title compound, C(28)H(19)NO(2), was synthesized by the reaction of 1,3-benzodioxole-5-carbaldehyde with naphthalen-2-amine catalyzed by thio-salicylic acid in acetic acid. The central dihydropyridine ring adopts a boat conformation. The two planar (r.m.s. deviations = 0.0158 and 0.0552 Å) bicyclic parts make a dihedral angle of 16.16 (5)° with respect to each other. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and C-H⋯π inter-actions.
منابع مشابه
4-Methoxy-5-[4-(4-methoxy-1,3-benzodioxol-5-yl)perhydro-1H,3H-furo[3,4-c]furan-1-yl]-1,3-benzodioxole
The 1,3-benzodioxole ring systems in the title compound, C(22)H(22)O(8), are almost planar. The perhydro-furofuranyl system linking them adopts a distorted double-envelope conformation. Supra-molecular aggregation is effected by C-H⋯O, C-H⋯π and π-π [centroid-centroid distance of 3.755 Å, inter-planar distance of 3.633 Å and dihedral angle of 14.6°] inter-actions.
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